From the Service manual for my '05 ST4s:
Adjusting the throttle position
sensor
Insert the Memory Card into the
tester and access the "Throttle
position sensor" function in the
“Auxiliaries” menu. You can now
read the throttle position sensor
output voltage with the MASTER
throttle completely closed. The
reference value is 150 mV ±15.
If you encounter different values,
loosen screws (14) fixing the throttle
position sensor and, keeping the
MASTER throttle in its fully closed
position, turn the position sensor until
obtaining the prescribed reading.
Tighten throttle position sensor
screws (14).
Disconnect the Mathesis tester
from the throttle position sensor
and reconnect this latter to the
motorcycle wiring.
Adjustment of idle speed fuel -
air mixture ratio
Connect Mathesis power cable (2)
socket (B) to the motorcycle
diagnosis outlet (15).
Enter the “Autodiagnosis” menu and
select the motorcycle model.
If the procedure is performed
correctly the tester will connect up to
the motorcycle engine control unit.
Select the “Read parameters”
function.
Now choose the “Throttle position
sensor check“function.
Turn MASTER throttle adjuster
screw (9) until obtaining the following
throttle angle and voltage values: 2.6°
(3° for USA version).
If it has been disconnected, return the
throttle control cable into its pulley to
activate the throttle control and adjust
the travel (see “Adjusting the throttle
control cable” Sect. D 4).
Turn adjuster screw (9) until reading
the previously set throttle angle and
voltage values.
I know you probably don't have a Mathesis, but the rest of the info I found very useful. If you have VDST and a multimeter you should be able to make the adjustments.
Hope it helps.