The central issue with making this change is stability. A motorcycle is designed to return to its straight-ahead condition after hitting an object or bump in the road that causes the front wheel to deflect slightly to the right or left. In other words, it has to remain stable for a variety of road conditions, and motorcycle stability is foremost a safety issue.
The way dynamic stability is assured is to design a bike with enough distance between the point where the front wheel touches the road and the intersection point between the steering axis and the road. This is called the trail dimension.
A longer trail dimension increases the motorcycle's stability on straights, but will also negatively affect the motorcycle's turning effort, i.e., more rider's strength is required in corners and transitions. However, the more trail, the greater the ability of the bike to self-correct it's steering. It's a longer trail dimension, for example, that allows you to easily ride with no hands on some bicycles, but not others.
A shorter trail dimension, on the other hand, produces a lower opposing force to steering inputs. It's kind of like power steering. So the steering requires less rider strength, but larger handlebar displacements from bumps in the road and corners are fed back to the rider. Said another way, the shorter the trail, the more rider input that is needed to hold a line and the more responsive the bike feels since it is more sensitive to steering inputs.
The two superbike steering angle positions, 23°30' and 24°30' produce trail dimensions of 91 mm and 97 mm respectively. The wheelbase, also an important factor in stability, remains unaffected when you change it. As a comparison, the Monster steering angle is fixed at 24° and the trail dimension is 94 mm. Adjusting the trail dimension on most manufacturer's bikes is not an option.
As an aside, when you change to the steeper 23°30' position you loose a significant amount of steering lock making low speed U-turns more difficult. Also, the ignition steering head lock doesn’t engage in the steeper position.
Now, here's Ducati's warning: "Trail should only be altered after all the other (geometry and suspension) changes have been made and you are comfortable on the bike. If the bike displays any instability problems they need to be sorted out first, as this steering head angle change will magnify these characteristics."
(One reason, for example, is that part of its effect mimics changing the rear ride height.)
The Haynes Service manual goes on to say "Warning: The steering head angle must be set to the road position (longer trail) whenever the bike is used on the road. If the steering angle is set to the race position (shorter trail) ... the handling of the machine could become unpredictable on uneven road surfaces."
So, shortening the trail is considered unwise for street riding (unlike tracks) where bumps in corners, potholes and other road hazards repeatedly challenge your bikes steering stability. Here's a case where inexperienced or uninformed riders who set-up their street bike chassis geometry as racebikes are just looking for trouble.
Trying to mimic factory race bike set-ups can get you into trouble. It's central to racing that race bikes often need to sacrifice high-speed stability to handling. Riders may initially run the steeper steering head angle, but often, as they get faster, they realize they want more stability, not less.
To get more stability there are two things that Ducati typically changes on their racebikes: the triple clamps and the swingarm. They use triple clamps with less offset, typically 27 mm instead of the stock 36 mm, and use a 25 mm longer swingarm to increase the wheelbase. These changes to the triple clamps or the swingarm have the effect of moving the center of gravity forward which is the typical starting geometry of the Corsa race bikes.